Meteo 431 – Atmospheric Thermodynamics
Study guide for the second midterm exam
5 April 2002
If you know all the concepts in the list below, you should be able to
do well on the midterm exam. Be sure to review your quizzes and your homework
problems.
- The First Law of Thermodynamics: concept and equation (including
the meaning of each term). dU/dt= Q + W
- Ideal gas law: equation in two forms. pV = NkT and p =
r RT.
- Enthalpy: concept and equation. H=U+pV
- Adiabatic processes: concept and use.
- Dry adiabatic lapse rate.
- Stability and buoyancy: concepts and relation to lapse rate.
- Entropy: concept and equation. dS/dt = Q/T (in process for which
W=-pdV/dt)
- Reversible and irreversible processes: concepts and examples.
- The Second Law of Thermodynamics.
- Potential temperature: concept and equation.
Q = T (po/p) (g -1)/
g
- Carnot cycle: concept, individual processes, energy, and entropy.
- Efficiency of the Carnot cycle: equation.
h =1-Tlow/Thigh
- Measures of water vapor: mass mixing ratio, and specific humidity,
relative humidity
- The concepts of condensation and evaporation, and C/E = e/e
s
- Boiling: concept and change with altitude
- Dewpoint temperature: concept
- Saturation vapor pressure: concept
- Gibbs free energy: what it is, how we use it, and the equation:
G = H - TS
- Clausius-Clapeyron Equation: (1/es)de
s/dT = lv/RvT2
- Enthalpies of vaporization, fusion, and sublimation and how they relate
to each other
- Effects of the difference between the saturation vapor pressure over
ice and over liquid water
- How the van der Waals equation of state differs from the ideal gas
law
- Critical temperature: concept
- The water vapor phase diagram near the triple point (Figure 5.13
) and what it means
- Simple problems involving cooling, heating, expansion, and phase changes