Meteo 431 – Atmospheric Thermodynamics
Study guide for the second midterm exam
5 April 2002




If you know all the concepts in the list below, you should be able to do well on the midterm exam. Be sure to review your quizzes and your homework problems.

  1. The First Law of Thermodynamics: concept and equation (including the meaning of each term). dU/dt= Q + W
  2. Ideal gas law: equation in two forms. pV = NkT and p = r RT.
  3. Enthalpy: concept and equation. H=U+pV
  4. Adiabatic processes: concept and use.
  5. Dry adiabatic lapse rate.
  6. Stability and buoyancy: concepts and relation to lapse rate.
  7. Entropy: concept and equation. dS/dt = Q/T (in process for which W=-pdV/dt)
  8. Reversible and irreversible processes: concepts and examples.
  9. The Second Law of Thermodynamics.
  10. Potential temperature: concept and equation. Q = T (po/p) (g -1)/ g
  11. Carnot cycle: concept, individual processes, energy, and entropy.
  12. Efficiency of the Carnot cycle: equation. h =1-Tlow/Thigh
  13. Measures of water vapor: mass mixing ratio, and specific humidity, relative humidity
  14. The concepts of condensation and evaporation, and C/E = e/e s
  15. Boiling: concept and change with altitude
  16. Dewpoint temperature: concept
  17. Saturation vapor pressure: concept
  18. Gibbs free energy: what it is, how we use it, and the equation: G = H - TS
  19. Clausius-Clapeyron Equation:  (1/es)de s/dT = lv/RvT2
  20. Enthalpies of vaporization, fusion, and sublimation and how they relate to each other
  21. Effects of the difference between the saturation vapor pressure over ice and over liquid water
  22. How the van der Waals equation of state differs from the ideal gas law
  23. Critical temperature: concept
  24. The water vapor phase diagram near the triple point (Figure 5.13 ) and what it means
  25. Simple problems involving cooling, heating, expansion, and phase changes